Open the Table's properties, select the Indexes Tab, choose the Index in the list then press the Edit button.
See Edit Table Tutorial
Editing Index Properties
Select the Parent Table.
* The Parent Table lists will only be available when adding a new Index to the Schema.
If you are editing an existing Index, this lists will be disabled.
Setup the Index Name as required.
See Object Names for more information.
Use the buttons on the right to Add or Remove Indexed Columns.
Use the buttons on the left to adjust the order of your Indexed Columns.